Chapter Objectives
Chapter 7 - Quantum Theory & Atomic Structure -
Sections 7.1-7.4
7.1 - The Nature of Light
Concepts
- Be able to describe the characteristics of electromagnetic radiation in terms of amplitude, frequency, wavelength and speed.
- Assigned problems: 7.1, 7.2
- Be able to describe how particles and waves differ with respect to refraction, diffraction and interference.
- Be able to describe the quantization of energy and relate this to the absorption and emission of light energy by atoms and be able to calculate the energy of a photon.
- Sample problems: 7.2
- Assigned problems: 7.4, 7.6, 7.64
- Be able to explain the photoelectric effect, first proposed by Einstein, and how it relates to particle-like (photon) behavior of light energy.
- Assigned problems: 7.5, 7.6
Skills
- Be able to interconvert between wavelength and frequency.
- Sample problem: 7.1
- Assigned problems: 7.8, 7.10, 7.13, 7.14, 7.85
- Be able to calcualte the energy of a photon from its wavelength.
- Sample problems: 7.2
- Assigned problems: 7.11
7.2 - Atomic Spectra
Concepts
- Be able to describe Bohr’s theory of the atom and how it was able to explain the line spectrum for the hydrogen atom.
- Assigned problems: 7.17, 7.18, 7.20, 7.21, 7.22
Skills
- Be able to find the energy change and wavelength a photon absorbed or emited when an H atom's electron changes energy level.
- Sample problem: 7.3
- Assigned problems: 7.23, 7.26, 7.27, 7.29, 7.34
7.3 - The Wave-Particle Duality of Matter and Energy
Concepts
- Be able to explain the wave-particle duality of matter and energy and the relevant theories and experiments that let to it (de Broglie wavelength, electron diffraction, photon momentum).
- Assigned problems 7.35, 7.37
- Be able to describe Heisenberg’s uncertainty principle and how it limits our knowledge about electrons in atoms.
Skills
- Be able to apply de Broglie's equation to find the wavelength of an electron or other object.
- Sample problem: 7.4
- Assigned problems: 7.39, 7.41, 7.68, 7.89
- Be able to apply the uncertainty principle to see that the location and speed of a particle cannot be determined simultaneously
- Sample problem 7.5
7.4 - The Quantum_Mechanical Model of the Atom
Concepts
- Be able to describe and distinguish between ψ, the wavefunction for an atomic orbital, and ψ2, the probability density function for an atomic orbital.
- Be able to describe how the electron density diagrams and radial probability distribution plots depict the electron location within an atom.
- Be able to discuss how the hierarchy of the quantum number describe the size, shape and orientation of an atomic orbital.
- Be able to distinguish between a shell (an energy level), a subshell (a sub energy level), and an orbital.
- Be able to describe the shapes and nodes for the s, p, and d orbitals.
Skills
- Be able to determine quantum numbers and sublevel designations .
- Sample problems 7.6, 7.7, 7.8
- Assigned problems:
7.49, 7.51, 7.53, 7.55, 7.57, 7.78